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Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - RUPES
Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 ZEPHIR/1 Page n. 4 of 10 7.1. Precautions for safe handling Avoid contact with skin and eyes, inhaltion of vapours and mists.
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Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 Safety Data Sheet dated 29/9/2016, version 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 Trade code: ZEPHIR 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Professional use only Uses advised against: All not indicated in the suggested uses. 1.3. Details of the supplier of the safety data sheet Company: RUPES SPA - Via Marconi 3A, 20080, Vermezzo (MI) Italy RUPES SPA - Telefono n°+3902946941 Competent person responsible for the safety data sheet: [email protected] 1.4. Emergency telephone number For United States, Canada Puerto Rico and Virgin Island: 1-800-255-3924 For China: 400-120-0751 For Brazil: 0-800-591-6042 For India: 000-800-100-4086 For Mexico: 01-800-099-0731 For Europe and all the other countries: 001-813-248-0585 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture EC regulation criteria 1272/2008 (CLP) The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Adverse physicochemical, human health and environmental effects: No other hazards 2.2. Label elements Hazard pictograms: None Hazard statements: None Precautionary statements: P102 Keep out of reach of children. Special Provisions: EUH210 Safety data sheet available on request. Special provisions according to Annex XVII of REACH and subsequent amendments: None ZEPHIR/1 Page n. 1 of 10 Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 2.3. Other hazards vPvB Substances: None - PBT Substances: None Other Hazards: No other hazards SECTION 3: Composition/information on ingredients 3.1. Substances N.A. 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: Qty >= 12.5% < 15% >= 3% < 5% 1 ppm Name Ident. Number Classification aliphatic hydrocarbons, CAS: C11-C13, isoalkanes EC: 64742-48-9 920-901-0 3.10/1 Asp. Tox. 1 H304 EUH066 REACH No.: 01-21194568 10-40 White mineral oil (petroleum) CAS: EC: 8042-47-5 232-455-8 3.10/1 Asp. Tox. 1 H304 REACH No.: 01-21194870 78-27 reaction mass of: Index 5-chloro-2-methyl-4-iso number: thiazolin-3-one [EC no. CAS: 247-500-7]; 613-167-00-5 3.2/1B Skin Corr. 1B H314 55965-84-9 3.4.2/1-1A-1B Skin Sens. 1,1A,1B H317 4.1/A1 Aquatic Acute 1 H400 4.1/C1 Aquatic Chronic 1 H410 3.1/3/Oral Acute Tox. 3 H301 3.1/3/Dermal Acute Tox. 3 H311 3.1/3/Inhal Acute Tox. 3 H331 SECTION 4: First aid measures 4.1. Description of first aid measures In case of skin contact: Wash with plenty of water and soap. In case of eyes contact: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of Ingestion: ZEPHIR/1 Page n. 2 of 10 Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY. In case of Inhalation: Remove casualty to fresh air and keep warm and at rest. 4.2. Most important symptoms and effects, both acute and delayed None 4.3. Indication of any immediate medical attention and special treatment needed Treatment: None SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: None in particular. 5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke. 5.3. Advice for firefighters Use suitable breathing apparatus . Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove all sources of ignition. Remove persons to safety. See protective measures under point 7 and 8. 6.2. Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand 6.3. Methods and material for containment and cleaning up Wash with plenty of water. 6.4. Reference to other sections See also section 8 and 13 SECTION 7: Handling and storage ZEPHIR/1 Page n. 3 of 10 Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 7.1. Precautions for safe handling Avoid contact with skin and eyes, inhaltion of vapours and mists. Don't use empty container before they have been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers. Contamined clothing should be changed before entering eating areas. Do not eat or drink while working. See also section 8 for recommended protective equipment. 7.2. Conditions for safe storage, including any incompatibilities Keep container closed when not in use. Keep only in the original container in a cool, well ventilated place away from: direct sunlight, heat and ignition sources Keep away from food, drink and feed. Incompatible materials: None in particular. Instructions as regards storage premises: Adequately ventilated premises. 7.3. Specific end use(s) Professional use only SECTION 8: Exposure controls/personal protection 8.1. Control parameters No occupational exposure limit available DNEL Exposure Limit Values 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 ppm PNEC Exposure Limit Values N.A. 8.2. Exposure controls Eye protection: Wear eye/face protection Protection for skin: Chemical protection clothing. Protection for hands: When handling with chemical substances, protective gloves must be worn with the CE-Label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances Respiratory protection: Filtering Half-face mask (DIN EN 149). Thermal Hazards: None Environmental exposure controls: None Appropriate engineering controls: None ZEPHIR/1 Page n. 4 of 10 Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Properties Appearance and colour: Odour: Odour threshold: pH: Melting point / freezing point: Initial boiling point and boiling range: Flash point: Evaporation rate: Solid/gas flammability: Upper/lower flammability or explosive limits: Vapour pressure: Vapour density: Relative density: Solubility in water: Solubility in oil: Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: Explosive properties: Oxidizing properties: Value White pasty characteristic N.A. 7.8 N.A. Method: ------ 100 ° C -- >61 ° C -- N.A. -- N.A. -- N.A. -- 0.4hPa g/cm3 -- N.A. -- 1.08g/cm3 -- Not soluble -- N.A. -- N.A. -- N.A. -- N.A. -- 25000-30000 -- mPa/s N.A. -- N.A. -- Notes ---at 20°C -- -- ----- ------- --- at 20°C --- 9.2. Other information Properties Miscibility: Fat Solubility: Conductivity: Substance Groups relevant properties Value N.A. N.A. N.A. 19.5% Method: ----- Notes ---content solvent SECTION 10: Stability and reactivity ZEPHIR/1 Page n. 5 of 10 Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 10.1. Reactivity No dangerous reactions known 10.2. Chemical stability stable under normal conditions 10.3. Possibility of hazardous reactions No dangerous reactions known 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures 10.5. Incompatible materials None in particular. 10.6. Hazardous decomposition products None. SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicological information of the mixture: N.A. Toxicological information of the main substances found in the mixture: aliphatic hydrocarbons, C11-C13, isoalkanes - CAS: 64742-48-9 a) acute toxicity: Test: LD50 - Route: Oral - Species: Rat = 5000 mg/kg - Source: OECD-Richtlinien 401 Test: LD50 - Route: Skin - Species: Rat = 5000 mg/kg - Source: OECD-Richtlinien 402 White mineral oil (petroleum) - CAS: 8042-47-5 a) acute toxicity: Test: LD50 - Route: Oral - Species: Rat > 5000 mg/kg - Source: OECD 401 Test: LD50 - Route: Skin - Species: Rabbit > 2000 mg/kg - Source: OECD 402 Test: LD50 - Route: Inhalation - Species: Rat > 5000 mg/l - Duration: 4h - Source: OECD 403 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7]; and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-6] (3:1); reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7]; and 2-methyl-4-isothiazolin-3-one [EC - CAS: 55965-84-9 a) acute toxicity: Test: ATE - Route: Oral = 100 mg/kg Test: ATE - Route: Skin = 300 mg/kg Test: ATE - Route: Inhalation Vapour = 3 mg/l Test: ATE - Route: Inhalation Mist = 0.5 mg/l If not differently specified, the information required in Regulation (EU)2015/830 listed below must be considered as N.A.: a) acute toxicity; b) skin corrosion/irritation; c) serious eye damage/irritation; d) respiratory or skin sensitisation; e) germ cell mutagenicity; ZEPHIR/1 Page n. 6 of 10 Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 f) carcinogenicity; g) reproductive toxicity; h) STOT-single exposure; i) STOT-repeated exposure; j) aspiration hazard. SECTION 12: Ecological information 12.1. Toxicity Adopt good working practices, so that the product is not released into the environment. White mineral oil (petroleum) - CAS: 8042-47-5 a) Aquatic acute toxicity: Endpoint: LC50 - Species: Fish > 1000 mg/l - Duration h: 96 12.2. Persistence and degradability 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 Biodegradability: Readily biodegradable - Test: N.A. - Duration h: N.A. - %: N.A. Notes: N.A. 12.3. Bioaccumulative potential N.A. 12.4. Mobility in soil 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 Not mobile - Test: N.A. N.A. - Duration h: N.A. - Notes: N.A. 12.5. Results of PBT and vPvB assessment vPvB Substances: None - PBT Substances: None 12.6. Other adverse effects None SECTION 13: Disposal considerations 13.1. Waste treatment methods Recover if possible. In so doing, comply with the local and national regulations currently in force. SECTION 14: Transport information 14.1. UN number Not classified as dangerous in the meaning of transport regulations. 14.2. UN proper shipping name N.A. 14.3. Transport hazard class(es) N.A. 14.4. Packing group N.A. 14.5. Environmental hazards N.A. 14.6. Special precautions for user ZEPHIR/1 Page n. 7 of 10 Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 N.A. 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code N.A. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Dir. 98/24/EC (Risks related to chemical agents at work) Dir. 2000/39/EC (Occupational exposure limit values) Regulation (EC) n. 1907/2006 (REACH) Regulation (EC) n. 1272/2008 (CLP) Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013 Regulation (EU) 2015/830 Regulation (EU) n. 286/2011 (ATP 2 CLP) Regulation (EU) n. 618/2012 (ATP 3 CLP) Regulation (EU) n. 487/2013 (ATP 4 CLP) Regulation (EU) n. 944/2013 (ATP 5 CLP) Regulation (EU) n. 605/2014 (ATP 6 CLP) Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications: Restrictions related to the product: No restriction. Restrictions related to the substances contained: No restriction. Where applicable, refer to the following regulatory provisions : Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent amendments. Regulation (EC) nr 648/2004 (detergents). 1999/13/EC (VOC directive) Provisions related to directive EU 2012/18 (Seveso III): N.A. 15.2. Chemical safety assessment No SECTION 16: Other information Full text of phrases referred to in Section 3: H304 May be fatal if swallowed and enters airways. EUH066 Repeated exposure may cause skin dryness or cracking. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H301 Toxic if swallowed. H311 Toxic in contact with skin. ZEPHIR/1 Page n. 8 of 10 Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 H331 Toxic if inhaled. This document was prepared by a competent person who has received appropriate training. Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This MSDS cancels and replaces any preceding release. ADR: CAS: CLP: DNEL: EINECS: GefStoffVO: GHS: IATA: IATA-DGR: ICAO: ICAO-TI: IMDG: INCI: KSt: LC50: LD50: LTE: PNEC: RID: STE: STEL: STOT: TLV: TWATLV: WGK: European Agreement concerning the International Carriage of Dangerous Goods by Road. Chemical Abstracts Service (division of the American Chemical Society). Classification, Labeling, Packaging. Derived No Effect Level. European Inventory of Existing Commercial Chemical Substances. Ordinance on Hazardous Substances, Germany. Globally Harmonized System of Classification and Labeling of Chemicals. International Air Transport Association. Dangerous Goods Regulation by the "International Air Transport Association" (IATA). International Civil Aviation Organization. Technical Instructions by the "International Civil Aviation Organization" (ICAO). International Maritime Code for Dangerous Goods. International Nomenclature of Cosmetic Ingredients. Explosion coefficient. Lethal concentration, for 50 percent of test population. Lethal dose, for 50 percent of test population. Long-term exposure. Predicted No Effect Concentration. Regulation Concerning the International Transport of Dangerous Goods by Rail. Short-term exposure. Short Term Exposure limit. Specific Target Organ Toxicity. Threshold Limiting Value. Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard). German Water Hazard Class. ZEPHIR/1 Page n. 9 of 10 Safety Data Sheet 9.BFZEPHIR/8 - 9.BFZEPHIR250/6 - 9.BFZEPHIR150/6 ZEPHIR/1 Page n. 10 of 10PDFCreator 2.1.2.0